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Cannon shot is relatively cheap, most expensive being around 10 gold i think, could be wrong on that as i don't have all the skills yet. I'm cannon level 9 with my current pirate and have chain, grape shot and flame skills. On my last pirate I got the thunder/lightning shot on level 10 or 12. A friend of mine just got the explosive skill last night at level 17 and you get fury at level 20 I've read.
As for the amounts you can carry, chain shot and grape you can carry 100 of each. For flame and thunder shot you can only carry 50 each. I don't know about the last 2 as I have not made it that far yet.
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