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I am not sure what you mean exactly by rank. If you have more points in throw or long volley that will add damage to all of the differant grenade types.
By rank if you are refering to higher level grenades that unlocked, they all do differant values. Stink pot and fire the same being less than explosive, as smoke doing less than them all. You want to do alot of damage and less throws/time, you will also end up getting less rep, as Sarah stated. You should use hex shot on gypsies or something, than grenades, so then you don't have to use tonics.
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